Methyl Acetate CAS# 79-20-9

Chemical name: methyl acetate
Subform: C₃H₆O₂
Molecular weight: 74.08
Appearance: Colorless transparent liquid, with aromatic smell, similar to fruit aroma.
Melting point: -98.7℃
Boiling point: 57.8℃
Density: 0.932 g/cm³ (20℃)
Refractive index: 1.3614 (20℃)
Solubility: slightly soluble in water, can be miscible with ethanol, ether, chloroform and most other organic solvents.
Flash point: -10℃ (closed cup)

Category:

Methyl Acetate CAS# 79-20-9

Methyl acetate Chemical Properties
Melting point -98 °C (lit.)
Boiling point 57-58 °C (lit.)
density 0.934 g/mL at 25 °C
vapor density 2.55 (vs air)
vapor pressure 165 mm Hg ( 20 °C)
refractive index n20/D 1.361(lit.)
FEMA 2676 | METHYL ACETATE
Fp 3.2 °F
storage temp. no restrictions.
solubility 250g/l
form Solution
color Clear colorless to slightly pale yellow
Relative polarity 0.253
Odor Slightly acrid, sweet; fragrant.
PH 7
biological source synthetic
Odor Type ethereal
Odor Threshold 1.7ppm
explosive limit 3.1-16%(V)
Water Solubility 250 g/L (20 ºC)
λmax λ: 255 nm Amax: 1.0
λ: 275 nm Amax: 0.1
λ: 300 nm Amax: 0.01
JECFA Number 125
Merck 14,6008
BRN 1736662
Henry’s Law Constant 0.90 at 20.00 °C, 1.56 at 30.00 °C (headspace-GC, Hovorka et al., 2002)
Exposure limits TLV-TWA 200 ppm (~610 mg/m3) (ACGIH, MSHA, and OSHA); TLV-STEL 250 ppm (~760 mg/m3) (ACGIH); IDLH 10,000 ppm (NIOSH).
Dielectric constant 7.3(20℃)
Stability: Stable. Extremely flammable – readily forms explosive mixtures with air. Note low flash point and wide explosion limits. Incompatible with strong oxidizing agents, strong bases, strong acids, nitrates. May be moisture sensitive.
LogP 0.18 at 20℃
CAS DataBase Reference 79-20-9(CAS DataBase Reference)
NIST Chemistry Reference Acetic acid, methyl ester(79-20-9)
EPA Substance Registry System Methyl acetate (79-20-9)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36-66-67
Safety Statements 16-26-29-33
RIDADR UN 1231 3/PG 2
OEB A
OEL TWA: 200 ppm (610 mg/m3), STEL: 250 ppm (760 mg/m3)
WGK Germany 1
RTECS AI9100000
Autoignition Temperature 936 °F
TSCA Yes
HS Code 2915 39 00
HazardClass 3
PackingGroup II
Hazardous Substances Data 79-20-9(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rat > 2000 mg/kg
IDLA 3,100 ppm [10% LEL]