4-Aminophenol CAS # 123-30-8

4-Aminophenol (or para-aminophenol or p-aminophenol) (123-30-8) is the natural compound with the components H2NC6H4OH, belongs to the category of natural compounds recognised as aniline and substituted anilines.
Typically on hand as a white powder, it was once generally used as a developer for black-and-white film, marketed below the identify Rodinal.
Reflecting its barely hydrophilic character, the white powder is reasonably soluble in alcohols and can be recrystallized from warm water. In the presence of a base, it oxidizes readily. The methylated derivatives N-methylaminophenol and N,N-dimethylaminophenol are of business value.
The compound is one of three isomeric aminophenols, the different two being 2-aminophenol and 3-aminophenol.

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4-Aminophenol CAS # 123-30-8

4-Aminophenol Chemical Properties
Melting point 188 °C
Boiling point 284 °C
density 1.29
vapor pressure 0.4 hPa (110 °C)
refractive index 1.5444 (estimate)
Fp 189 °C
storage temp. 2-8°C
solubility water: slightly soluble
form Crystalline Powder
pka 5.48, 10.30(at 25℃)
color White to cream
Water Solubility 1.5 g/100 mL (20 ºC)
Sensitive Air & Light Sensitive
Decomposition 284 °C
Merck 14,462
BRN 385836
Stability: Stable, though may discolour in air. Incompatible with acids, chloroformates, strong oxidizing agents.
InChIKey PLIKAWJENQZMHA-UHFFFAOYSA-N
LogP -0.09-0.04 at 25℃
CAS DataBase Reference 123-30-8(CAS DataBase Reference)
NIST Chemistry Reference Phenol, 4-amino-(123-30-8)
EPA Substance Registry System p-Aminophenol (123-30-8)
Safety Information
Hazard Codes Xn,N
Risk Statements 20/22-50/53-68-40-R68-R50/53-R20/22
Safety Statements 28-36/37-60-61-28A-S61-S60-S36/37-S28A
RIDADR UN 2512 6.1/PG 3
WGK Germany 3
RTECS SJ5075000
F 8
Autoignition Temperature >250 °C
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 28402090
HS Code 29222900
Hazardous Substances Data 123-30-8(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 375 mg/kg LD50 dermal Rabbit > 10000 mg/kg